Pandey, Ganesh ; Pooranchand, Dinah ; Bhalerao, U. T. (1991) Photoinduced single electron transfer activation of organophosphines: nucleophilic trapping of phosphine radical cation Tetrahedron, 47 (9). pp. 1745-1752. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4020(01)96916-9
Abstract
Photophysical studies show that organophosphines (1-4) form charge transfer stabilized exciplex with excited singlet 1DCN∗ . One electron oxidation of phosphines to corresponding radical cation via phosphine... 1DCN∗ electron donor, acceptor pair dissociation is reported. Phosphine radical cations are lound to react readily with moisture to give phosphine oxides.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 60967 |
| Deposited On: | 13 Sep 2011 11:20 |
| Last Modified: | 13 Sep 2011 11:20 |
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