Jana, Anukul ; Sen, Sakya S. ; Roesky, Herbert W. ; Schulzke, Carola ; Dutta, Sudipta ; Pati, Swapan K. (2009) End-on nitrogen insertion of a diazo compound into a germanium (II) hydrogen bond and a comparable reaction with diethyl azodicarboxylate Angewandte Chemie International Edition, 48 (23). pp. 4246-4248. ISSN 1433-7851
Full text not available from this repository.
Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...
Related URL: http://dx.doi.org/10.1002/anie.200900617
Abstract
A happy ending: The germanium(II) hydride [LGeH], where L=[HC{(CMe)(2,6-iPr2C6H3N)}2], reacts with a diazoalkane to form the hydrazone derivative (see picture). The reaction proceeds through the unprecedented end-on nitrogen insertion of the diazo compound.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Ab Initio Calculations; Diazo Compounds; Insertions; Germanium |
| ID Code: | 60842 |
| Deposited On: | 12 Sep 2011 07:23 |
| Last Modified: | 12 Sep 2011 07:23 |
Repository Staff Only: item control page
