Studies on oxidations with IBX: oxidation of alcohols and aldehydes under solvent-free conditions

Narasimha Moorthy, Jarugu ; Singhal, Nidhi ; Venkatakrishnan, P. (2004) Studies on oxidations with IBX: oxidation of alcohols and aldehydes under solvent-free conditions Tetrahedron Letters, 45 (28). pp. 5419-5424. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2004.05.044

Abstract

A variety of allylic and benzylic alcohols are oxidized to their respective carbonyl compounds with IBX under solvent-free conditions at ca. 60-70 °C. It has also been found that some of the aromatic aldehydes also undergo oxidation when heated with IBX at 90 °C under solvent-free conditions; notably, this transformation does not occur under the otherwise identical but heterogeneous conditions.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:IBX; Oxidations; Solvent-free; Alcohols
ID Code:60726
Deposited On:10 Sep 2011 11:37
Last Modified:10 Sep 2011 11:37

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