Narasimha Moorthy, Jarugu ; Singhal, Nidhi ; Senapati, Kalyan (2006) Oxidations with IBX: benzyl halides to carbonyl compounds, and the one-pot conversion of olefins to 1,2-diketones Tetrahedron Letters, 47 (11). pp. 1757-1761. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2006.01.039
Abstract
A variety of benzyl halides were converted to the corresponding aldehydes/ketones in respectable yields by IBX in DMSO at 65°C. The bromohydrin reaction of olefins using NBS-H2O in DMSO can be nicely adapted to IBX-mediated oxidation of benzyl halides in such a way that olefins are converted to the corresponding 1,2-diketones in good isolated yields in one-pot.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 60723 |
| Deposited On: | 10 Sep 2011 11:39 |
| Last Modified: | 10 Sep 2011 11:39 |
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