Narasimha Moorthy, J. ; Natarajan, R. ; Venugopalan, P. (2002) Characterization of a planar cyclic form of water hexamer in an organic supramolecular complex: an unusual self-assembly of bimesityl-3,3'-dicarboxylic acid Angewandte Chemie International Edition, 41 (18). pp. 3417-3420. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/1521-37...
Related URL: http://dx.doi.org/10.1002/1521-3773(20020916)41:18<3417::AID-ANIE3417>3.0.CO;2-B
Abstract
Trapped water: Six molecules of water are trapped in the crystal lattice of an organic supramolecular complex with bimesityl-3,3'-dicarboxylic acid in the form of a planar cyclic "ring", which is the basic structural motif of Ice II. The water molecules of the hexamer (see picture) are associated in the crystal lattice by eighteen O-H···O hydrogen bonds.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Carboxylic Acids; Cluster Compounds; Hydrogen Bonds; Supramolecular Chemistry; Water Chemistry |
| ID Code: | 60719 |
| Deposited On: | 10 Sep 2011 11:37 |
| Last Modified: | 10 Sep 2011 11:37 |
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