Yadav, J. S. ; Satyanarayana Reddy, P. (1986) Allylation of Grignard reagents: its application for the synthesis of (4E, 7Z)-4,7-tridecadienyl acetate, a sex pheromone of potato tuberworm moth Synthetic Communications, 16 (9). pp. 1119-1131. ISSN 0039-7911
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Official URL: http://www.tandfonline.com/doi/abs/10.1080/0039791...
Related URL: http://dx.doi.org/10.1080/00397918608056355
Abstract
Alkylmagnesium halides have been found to react with (Z)-4-benzyloxy-1-chloro-2-butene in presence of HMPA to produce a rearranged product 3-alkyl-4-benzyloxy-1-butene, while in absence of HMPA a normal product (Z)-1-alkyl-4-benzyloxy-2-butene resulted as the predominant product. Latter product has been utilized for the synthesis of (4E, 7Z)-4,7-tridecadienyl acetate, a sex pheromone of potato tuberworm moth.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Taylor and Francis Group. |
| ID Code: | 60464 |
| Deposited On: | 09 Sep 2011 03:44 |
| Last Modified: | 09 Sep 2011 03:44 |
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