Yadav, J. S. ; Subba Reddy, B. V. ; Murthy, C. V. S. R. ; Mahesh Kumar, G. (2000) Scandium triflate catalyzed Ferrier rearrangement: an efficient synthesis of 2,3-unsaturated glycopyranosides Synlett, 2000 (10). pp. 1450-1451. ISSN 0936-5214
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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...
Related URL: http://dx.doi.org/10.1055/s-2000-7632
Abstract
Scandium(III) trifluoromethanesulfonate is found to catalyze efficiently the O-glycosidation of 3,4,6-tri-O-acetyl-d-glucal with various alcohols and phenols to afford the corresponding 2,3-unsaturated glycosides in excellent yields with good anomeric selectivity.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Glucal; Scandium Triflate; Ferrier Rearrangement; Glycosides |
| ID Code: | 60453 |
| Deposited On: | 09 Sep 2011 03:48 |
| Last Modified: | 09 Sep 2011 03:48 |
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