Scandium triflate immobilized in ionic liquids: a novel and recyclable catalytic system for hetero-Diels-Alder reactions

Yadav, J. S. ; Reddy, B. V. S. ; Uma Gayathri, K. ; Prasad, A. R. (2002) Scandium triflate immobilized in ionic liquids: a novel and recyclable catalytic system for hetero-Diels-Alder reactions Synthesis, 2002 (17). pp. 2537-2541. ISSN 0039-7881

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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...

Related URL: http://dx.doi.org/10.1055/s-2002-35627

Abstract

Cyclic enol ethers such as 3,4-dihydro-2H-pyran (DHP) and 2,3-dihydrofuran (DHF) undergo [4+2] cycloaddition reactions with imines (generated in situ from aryl amines and enol ethers) in the presence of 3 mol% scandium triflate immobilized in 1-butyl-3-methylimidazolium hexafluorophosphate under solvent-free conditions to afford the corresponding pyrano- and furo[3,2-c]quinolines in high yields.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Ionic Liquids; Scandium Triflate; Hetero-Diels-Alder Reaction; Cis-fused Tetrahydroquinolines
ID Code:60449
Deposited On:09 Sep 2011 03:49
Last Modified:09 Sep 2011 03:49

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