Sabitha, Gowravaram ; Satheesh Babu, R. ; Rajkumar, M. ; Srividya, R. ; Yadav, J. S. (2001) A highly efficient, mild, and selective cleavage of β-methoxyethoxymethyl (MEM) ethers by cerium(III) chloride in acetonitrile Organic Letters, 3 (8). pp. 1149-1151. ISSN 1523-7060
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol015585w
Related URL: http://dx.doi.org/10.1021/ol015585w
Abstract
A highly selective cleavage of MEM ethers has been achieved in high yields using CeCl3·7H2O in refluxing acetonitrile under mild and neutral reaction conditions. The method is very rapid and compatible with other hydroxyl protecting groups such as Bn, TBDPS, Ac, Me, Tr, PMB, benzylidene, THP, MOM, BOM, and NHAc present in the substrate.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 60438 |
| Deposited On: | 09 Sep 2011 03:49 |
| Last Modified: | 09 Sep 2011 03:49 |
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