Sabitha, Gowravaram ; Satheesh Babu, R. ; Rajkumar, M. ; Yadav, J. S. (2002) Cerium(III) chloride promoted highly regioselective ring opening of epoxides and aziridines using NaN3 in acetonitrile: a facile synthesis of 1,2-azidoalcohols and 1,2-azidoamines Organic Letters, 4 (3). pp. 343-345. ISSN 1523-7060
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol016979q
Related URL: http://dx.doi.org/10.1021/ol016979q
Abstract
A convenient and efficient synthesis of 1,2-azidoalcohols and 1,2-azidoamines has been achieved by ring opening of epoxides and aziridines using cerium(III) chloride and sodium azide in acetonitrile. The reaction is highly regioselective and afforded the corresponding products in good to excellent yields under mild and neutral reaction conditions. The method is very rapid and equally compatible for both epoxides and aziridines.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 60431 |
| Deposited On: | 09 Sep 2011 03:49 |
| Last Modified: | 09 Sep 2011 03:49 |
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