Yadav, J. S. ; Soman, R. ; Sobti, R. R. ; Nayak, U. R. ; Dev, Sukh (1980) Studies in sesquiterpenes-LVI : Isolongifolene (part 7): mechanism of rearrangement of longifolene to isolongifolene-II Tetrahedron, 36 (14). pp. 2105-2111. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0040-4020(80)80099-8
Abstract
The question of possible neutral intermediates which may lie on the reaction pathway in going from longifolene to isolongifolene has been investigated using BF3·Et2O-AcOD and D3PO4-dioxane, as reagents. It has been found that longicyclene is not an obligatory intermediate. The mode of cleavage of cyclopropane ring in longicyclene has been investigated.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 60416 |
| Deposited On: | 09 Sep 2011 03:44 |
| Last Modified: | 23 Jun 2012 12:05 |
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