Yadav, J. S. ; Subba Reddy, B. V. ; Biswas, Swapan Kumar ; Sengupta, Sandip ; Vishnumurthy, P. (2008) Indium-mediated vic-diallylation/propargylation of phenacyl bromides: a facile synthesis of 4-arylocta-1,7-dien-4-ol derivatives Tetrahedron Letters, 49 (6). pp. 1034-1036. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2007.12.005
Abstract
Phenacyl bromides undergo smooth vic-diallylation and dipropargylation with allyl and propargyl indium reagents generated in situ from metallic indium and allyl or propargyl bromide to produce 4-arylocta-1,7-dien-4-ol derivatives in good yields. Phenacyl chloride and azide also participated effectively in bis-allylation. Similar results are also obtained from in situ generated allyl or propargyl zinc bromide.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
Keywords: | Indium Metal; Phenacyl Bromide; vic-diallylation; Propargylation; C-C Bond Formation |
ID Code: | 60404 |
Deposited On: | 09 Sep 2011 03:55 |
Last Modified: | 09 Sep 2011 03:55 |
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