Ansari, I. A. ; Joyasawal, Sipak ; Gupta, Manoj K. ; Yadav, J. S. ; Gree, R. (2005) Wacker oxidation of terminal olefins in a mixture of [bmim][BF4] and water Tetrahedron Letters, 46 (44). pp. 7507-7510. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2005.09.013
Abstract
A simple and efficient PdCl2/CuCl catalyzed oxidation of alkenes has been successfully developed using a mixture of water and the ionic liquid [bmim][BF4] as solvent. Starting from various types of terminal olefins, the corresponding ketones have been prepared under mild reaction conditions and obtained in good to excellent yields after a simple extraction with diethyl ether. Furthermore, it was possible to recycle and reuse the ionic liquid and the catalytic system.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Wacker Oxidation; Ionic Liquid; PdCl2; CuCl; Alkenes |
| ID Code: | 60395 |
| Deposited On: | 09 Sep 2011 03:54 |
| Last Modified: | 09 Sep 2011 03:54 |
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