Novel co-operative magnetic properties of decamethylmanganocenium 2,3-dichloro-5,6-dicyanobenzoquinoneide, 3[Mn(C5Me5)2]:+[DDQ]:-

Miller, Joel S. ; McLean, R. Scott ; Vazquez, Carlos ; Yee, Gordon T. ; Narayan, K. S. ; Epstein, Arthur J. (1991) Novel co-operative magnetic properties of decamethylmanganocenium 2,3-dichloro-5,6-dicyanobenzoquinoneide, 3[Mn(C5Me5)2]:+[DDQ]:- Journal of Materials Chemistry, 1 (3). pp. 479-480. ISSN 1364-5501

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1991...

Related URL: http://dx.doi.org/10.1039/JM9910100479

Abstract

The electron-transfer salt 3[Mn(C5Me5)2]:+[DDQ]-, isomorphous to orthorhombic [Fe(C5Me5)2]+[DDQ]- , has been prepared. It exhibits a complex field- dependent magnetic pahse diagram at low temperatures with evidence for ferromagnetic coupling as well as a low moment state below 4 K for zero- field cooled samples.

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