From diamondoid network to (4, 4) net: effect of ligand topology on the supramolecular structural diversity

Krishna Kumar, D. ; Amilan Jose, D. ; Das, Amitava ; Dastidar, Parthasarathi (2005) From diamondoid network to (4, 4) net: effect of ligand topology on the supramolecular structural diversity Crystal Growth & Design, 44 (20). pp. 6933-6935. ISSN 1528-7483

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic050972d

Related URL: http://dx.doi.org/10.1021/ic050972d

Abstract

While N,N'-bis(4-pyridyl)urea affords a 5-fold interpenetrated diamondoid network, its positional isomer N,N'-bis(3-pyridyl)urea gave a net-to-net hydrogen-bonded (4,4) net (square grid network) displaying temperature-dependent anion-induced reversible single-crystal-to-single-crystal disorder-order phase transition, when the ligands are reacted with zinc perchlorate.

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Deposited On:08 Sep 2011 10:20
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