Das, Amitava ; McCleverty, Jon A. ; Ward, Michael D. ; Jones, Christopher J. ; Cargill Thompson, Alexander M. W. (1992) Intramolecular quenching of the excited state of a tris(2,2'-bipyridyl)ruthenium(II) chromophore by covalently linked electron-accepting metal centres Polyhedron, 11 (16). pp. 2119-2122. ISSN 0277-5387
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0277-5387(00)83170-8
Abstract
Reaction of 1 (a derivative of [Ru(bipy)3]2+ with an externally-directed pendant phenol ligand) with [ML*(NO)Cl2][L* = hydrotris(3,5-dimethyl)pyrazolylborate; M = Mo, W] results in heterobinuclear species 4 and 5, in which a [Ru(bipy)3]2+ chromophore is linked at the periphery to electron-accepting molybdenum or tungsten mononitrosyl complexes; this results in complete quenching of the dΠ(Ru)-Π*(bipy) 3m.l.c.t. excited state at room temperature.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 59916 |
| Deposited On: | 07 Sep 2011 14:17 |
| Last Modified: | 07 Sep 2011 14:17 |
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