Das, Amitava ; Jones, Christopher J. ; McCleverty, Jon A. (1993) Redox activity of bimetallic molybdenum and tungsten nitrosyls containing ligands based on 4-hydroxyphenylalkanols Polyhedron, 12 (3). pp. 327-336. ISSN 0277-5387
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0277-5387(00)81731-3
Abstract
The redox-active bimetallic complexes, [{M(NO)L*X}2Q] [L* = tris(3,5-dimethylpyrazolyl)borate, HB(3,5-Me2pyz)3; M = Mo, X = Cl or I; M = W, X = Cl; Q = OC6H4(CH2)nO (n = 1-3) or NHC6H4(CH2)nO (n = 2, 3)], have been prepared and characterized spectroscopically and electrochemically (cyclic voltammetry, coulometry). The electrochemical data indicate that there can be weak interactions between the two metal-based redox centres.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 59913 |
| Deposited On: | 07 Sep 2011 14:17 |
| Last Modified: | 07 Sep 2011 14:17 |
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