Das, Amitava ; Bajaj, H. C. (1997) Mixed valence complexes incorporating RuIII and FeII: synthesis, characterization, kinetics and physico-chemical studies Polyhedron, 16 (7). pp. 1023-1030. ISSN 0277-5387
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0277-5387(96)00415-9
Abstract
A set of new mixed valence complexes of the type Na3[(edtaH)RuIIILFeII(CN)5], where L = pyz, bp, dmbp, etybp or tmbp, has been synthesized and characterized by physico-chemical methods. The kinetics of formation of these binuclear complexes were studied using a stopped-flow spectrophotometer. Electrochemical studies for these complexes show only a weak metal-metal interaction in the ground state. All these complexes, except the one incorporating tmbp, gave an MMCT band in the region 900> λ > 1000 nm and belong to the Robin-Day class II type.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Synthesis; Ruthenium; Binuclear Complexes; Kinetics; Mixed-valence |
| ID Code: | 59910 |
| Deposited On: | 07 Sep 2011 14:17 |
| Last Modified: | 07 Sep 2011 14:17 |
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