Highly regioselective ring opening of epoxides and aziridines using cerium(III) chloride

Sabitha, Gowravaram ; Satheesh Babu, R. ; Rajkumar, M. ; Srinivas Reddy, Ch. ; Yadav, J. S. (2001) Highly regioselective ring opening of epoxides and aziridines using cerium(III) chloride Tetrahedron Letters, 42 (23). pp. 3955-3958. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(01)00622-0

Abstract

A wide variety of epoxides and aziridines were converted to the corresponding β-halohydrins and β-haloamines using cerium(III) chloride and the cerium(III) chloride/NaI system in acetonitrile. The reactions were highly regioselective and efficient with excellent yields under mild and neutral reaction conditions.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Regioselective; Cerium(III) Chloride; Epoxides; Aziridines
ID Code:59661
Deposited On:07 Sep 2011 05:29
Last Modified:07 Sep 2011 05:29

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