Yadav, J. S. ; Reddy, B. V. S. ; Swamy, T. (2003) Bi(OTf)3-catalyzed allylation of quinones with allyltrimethylsilane Tetrahedron Letters, 44 (26). pp. 4861-4864. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4039(03)01130-4
Abstract
p-Quinones react smoothly with allyltrimethylsilane in the presence of 2 mol% of Bi(OTf)3 under mild reaction conditions to afford the corresponding allyl substituted benzene derivatives, p-allylquinols and allyl substituted 1,4-naphthoquinones in excellent yields with high regioselectivity. This method is very useful for the direct introduction of an allyl functionality onto a quinone moiety.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Bismuth Triflate; Allylation; Quinones; Allyl Benzenes |
| ID Code: | 59657 |
| Deposited On: | 07 Sep 2011 05:34 |
| Last Modified: | 07 Sep 2011 05:34 |
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