Novel, efficient and stereospecific synthesis of xylo-(2R,3S,4S)-phytosphingosine and threo-(2R,3R)-sphingosine

Raghavan, Sadagopan ; Rajender, A. ; Yadav, J. S. (2003) Novel, efficient and stereospecific synthesis of xylo-(2R,3S,4S)-phytosphingosine and threo-(2R,3R)-sphingosine Tetrahedron: Asymmetry, 14 (14). pp. 2093-2099. ISSN 0957-4166

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0957-4166(03)00427-0

Abstract

The stereo- and regioselective elaboration of a bromohydrin from an olefinic precursor and Pummerer ene reaction for carbon---carbon bond formation are the key steps in a novel and flexible synthesis of xylo-phytosphingosine and threo-sphingosine.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:59630
Deposited On:07 Sep 2011 05:34
Last Modified:07 Sep 2011 05:34

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