Yadav, J. S. ; Subba Reddy, B. V. ; Pratap Singh, Ashutosh ; Basak, A. K. (2007) IBX/Sc(OTf)3-promoted one-pot oxidative conjugate addition of allyltrimethylsilane to Baylis-Hillman adducts Tetrahedron Letters, 48 (42). pp. 7546-7548. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2007.07.198
Abstract
Baylis-Hillman adducts undergo smooth one-pot oxidative Michael addition with allyltrimethylsilane in the presence of 2-iodoxybenzoic acid (IBX)/Sc(OTf)3 under mild conditions to afford homoallyl β-ketoesters in good yields with high 1,4-selectivity.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Baylis-Hillman Adducts; Hypervalent Iodine; Allylsilane; Conjugate Addition |
| ID Code: | 59629 |
| Deposited On: | 07 Sep 2011 05:46 |
| Last Modified: | 07 Sep 2011 05:46 |
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