Yadav, J. S. ; Reddy, B. V. S. ; Shesha Rao, M. ; Reddy, P. N. (2003) LiClO4-catalyzed highly diastereoselective synthesis of cis-aziridine carboxylates Tetrahedron Letters, 44 (28). pp. 5275-5278. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4039(03)01264-4
Abstract
Aldimines (generated in situ from aldehydes and amines) undergo ready addition with ethyl diazoacetate in the presence of a catalytic amount of lithium perchlorate in acetonitrile to afford the corresponding cis-aziridine carboxylates in high yields with high diastereoselectivity. 10 mol% LiClO4 in acetonitrile provides a convenient catalytic media to perform the reactions under mild and neutral conditions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 59625 |
| Deposited On: | 07 Sep 2011 05:34 |
| Last Modified: | 07 Sep 2011 05:34 |
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