Chelation-controlled reduction: an enantioselective synthesis of (−)-tarchonanthuslactone

Sabitha, Gowravaram ; Sudhakar, K. ; Mallikarjuna Reddy, N. ; Rajkumar, M. ; Yadav, J. S. (2005) Chelation-controlled reduction: an enantioselective synthesis of (−)-tarchonanthuslactone Tetrahedron Letters, 46 (38). pp. 6567-6570. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2005.07.075

Abstract

The total synthesis of tarchonanthuslactone (1) has been achieved by two different routes. In the first approach, LiAlH4-LiI reduction and RCM protocols, and in the second approach, Wacker oxidation and LiAlH4-LiI reduction were used as key steps.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Chelation-controlled Reduction; Tarchonanthuslactone; RCM; Wacker Oxidation
ID Code:59605
Deposited On:07 Sep 2011 05:41
Last Modified:07 Sep 2011 05:41

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