Yadav, J. S. ; Subba Reddy, B. V. ; Chand, Pratap K. (2001) Sc(OTf)3-catalyzed C-glycosidation of glycals: a facile synthesis of allyl glycosides, glycosyl cyanides and glycosyl azides Tetrahedron Letters, 42 (24). pp. 4057-4059. ISSN 0040-4039
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4039(01)00629-3
Abstract
The treatment of glycals with allyltrimethylsilane, trimethylsilyl cyanide and trimethylsilyl azide in the presence of catalytic amounts of Sc(OTf)3 gave the corresponding 2,3-unsaturated allyl glycosides, glycosyl cyanides and glycosyl azides in excellent yields with high α-selectivity.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Scandium Triflate; Glycals; C-glycosidation; 2,3-unsaturated Glycosides |
| ID Code: | 59575 |
| Deposited On: | 07 Sep 2011 05:29 |
| Last Modified: | 07 Sep 2011 05:29 |
Repository Staff Only: item control page
