Yadav, J. S. ; Subba Reddy, B. V. ; Basak, A. K. ; Narsaiah, A. V. ; Prabhakar, A. ; Jagadeesh, B. (2005) First example of the C-alkylation of indoles with Baylis-Hillman acetates Tetrahedron Letters, 46 (4). pp. 639-641. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2004.11.139
Abstract
Baylis-Hillman acetates undergo SN2' allylic substitution with indoles in the presence of 20 mol % of indium tribromide under mild conditions to afford a new class of substituted indoles in high yields with (E)-stereoselectivity. The stereochemistry of the products was assigned by various NMR experiments.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Indium Compounds; Allylic Substitution; Heteroaromatics |
| ID Code: | 59574 |
| Deposited On: | 07 Sep 2011 05:39 |
| Last Modified: | 07 Sep 2011 05:39 |
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