Yadav, J. S. ; Subba Reddy, B. V. ; Jyothirmai, B. ; Murty, M. S. R. (2005) Lithium perchlorate-catalyzed regioselective ring-opening of aziridines with potassium thiocyanate Tetrahedron Letters, 46 (37). pp. 6385-6387. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2005.06.165
Abstract
Aziridines react smoothly with potassium thiocyanate in the presence of a catalytic amount of lithium perchlorate in acetonitrile under mild reaction conditions to afford the corresponding β-aminothiocyanates in high yields and with high regioselectivity. The combination of lithium perchlorate and acetonitrile provides a convenient catalytic medium to perform the reactions under neutral conditions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Lithium Perchlorate; Aziridines; Potassium Thiocyanate; β-aminothiocyanates |
| ID Code: | 59565 |
| Deposited On: | 07 Sep 2011 05:41 |
| Last Modified: | 07 Sep 2011 05:41 |
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