InCl3/IBX: a novel reagent system for the conversion of glycals into α,β-unsaturated δ-lactones

Yadav, J. S. ; Subba Reddy, B. V. ; Suresh Reddy, Ch. (2004) InCl3/IBX: a novel reagent system for the conversion of glycals into α,β-unsaturated δ-lactones Tetrahedron Letters, 45 (23). pp. 4583-4585. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2004.03.081

Abstract

The combination of indium trichloride with iodoxybenzoic acid (IBX) has been utilized for the first time as a novel reagent system for the one-pot synthesis of 2,3-dideoxy-d-hex-2-enono-1,5-lactones from glycals. The reaction proceeds smoothly in aqueous media and the products are obtained in good yields. This method is suitable for the oxidation of glycals bearing olefin functionality.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Glycals; Indium Reagents; Hypervalent Iodine Reagents; Enelactones
ID Code:59558
Deposited On:07 Sep 2011 05:39
Last Modified:07 Sep 2011 05:39

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