Yadav, J. S. ; Das, Saibal ; Satyanarayana Reddy, J. ; Thrimurtulu, N. ; Prasad, A. R. (2010) The first stereo selective total synthesis of (3R),(5R)-5-hydroxy-de-O-methyllasiodiplodin and its epimer via an RCM protocol Tetrahedron Letters, 51 (31). pp. 4050-4052. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2010.05.115
Abstract
The first total synthesis of (3R),(5R)-5-hydroxy-de-O-methyllasiodiplodin and its epimer is reported from malic acid. The adopted approach is highly convergent and stereoselective. The strategy utilizes syn selective reduction and ring-closing metathesis as key steps.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
ID Code: | 59551 |
Deposited On: | 07 Sep 2011 05:58 |
Last Modified: | 07 Sep 2011 05:58 |
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