Müller, Achim ; Dommröse, Anne-Marie ; Jaegermann, Wolfram ; Krickemeyer, Erich ; Sarkar, Sabyasachi (1981) Determination of the structure of new tetrathiomolybdato complexes of FeII, CuI and AgI by the resonance raman effect: textbook examples for its application in coordination chemistry Angewandte Chemie International Edition, 20 (12). pp. 1061-1063. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.19...
Related URL: http://dx.doi.org/10.1002/anie.198110611
Abstract
Precursors with a high Fe content, such as (1), are especially suitable for the construction of the MoFe cofactor of nitrogenase. Reaction of AgNO3, (NH4)2MoS4 and PPh3 affords the symmetrical trinuclear complex (2). The structures of (1) and (2) and related compounds were determined by the Resonance-Raman-Effect method; the influence of the nearest and next nearest neighbors on the vibrations of the ligand chromophore is investigated.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| ID Code: | 59327 |
| Deposited On: | 06 Sep 2011 06:07 |
| Last Modified: | 06 Sep 2011 06:07 |
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