Selective inclusion of DMF molecules within non-covalent cavity

Maiti, Biplab K. ; Pal, Kuntal ; Sarkar, Sabyasachi (2011) Selective inclusion of DMF molecules within non-covalent cavity Inorganica Chimica Acta, 372 (1). pp. 213-219. ISSN 0020-1693

Full text not available from this repository.

Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.ica.2011.01.087

Abstract

[Me4P]4[Cu4(mnt)4]·2CH3CN (1), [Me4P]4[Cu4(mnt)4]·2CH3NO2 (2), [Me4P]4[Cu4(mnt)4]·2DMF (3) and [Me4P]4[Cu4(mnt)4]·2C3H3N (4) (mnt= maleonitriledithiolate, [S2C2(CN)2]2−) clusters are readily synthesized in several solvents like acetonitrile, nitromethane, N,N-dimethylformamide and acrylonitrile to provide respective solvent as guest within the non-covalent cavity of the cluster ion. The guest species is accommodated within non-covalent cavity that is generated by two adjacent {Cu4(mnt)4} cores bridging with tetramethylphosphonium cation through hydrogen bonding. These hydrogen bonds are not strong and when mixed solvents were used selective DMF binding takes place to yield only complex 3 over other complexes.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Cluster; Host-guest; Non-covalent Cavity; Hydrogen Bond
ID Code:59323
Deposited On:06 Sep 2011 06:16
Last Modified:06 Sep 2011 06:16

Repository Staff Only: item control page