Begum, Ameerunisha ; Moula, Golam ; Sarkar, Sabyasachi (2010) A nickel(II)-sulfur-based radical-ligand complex as a functional model of hydrogenase Chemistry - A European Journal, 16 (41). pp. 12324-12327. ISSN 0947-6539
Full text not available from this repository.
Official URL: http://onlinelibrary.wiley.com/doi/10.1002/chem.20...
Related URL: http://dx.doi.org/10.1002/chem.201001812
Abstract
A nickel(II) dithiolene complex [NiII(L2−)(L−.)][PPh4] (1; see figure; L=1,2-dicarbomethoxyethylene dithiolate) electrocatalyzes hydrogen evolution at the lowest achievable reduction potential (−0.69 V) in CH3CN and also in aqueous medium (−0.71 V) to date. Compound 1 shows strikingly similar EPR and reduction potential values to those observed with native Ni-containing hydrogenases.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Cyclic Voltammetry; Density Functional Calculations; EPR Spectroscopy; Hydrogen Evolution; Hydrogenases |
| ID Code: | 59317 |
| Deposited On: | 06 Sep 2011 06:13 |
| Last Modified: | 06 Sep 2011 06:13 |
Repository Staff Only: item control page
