Müller, Achim ; Krickemeyer, Erich ; Das, Samar K. ; Kögerler, Paul ; Sarkar, Sabyasachi ; Bögge, Hartmut ; Schmidtmann, Marc ; Sarkar, Shatarupa (2000) Linking icosahedral, strong molecular magnets {Mo} to layers-a solid-state reaction at room temperature Angewandte Chemie International Edition, 39 (9). pp. 1612-1614. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/(SICI)1...
Related URL: http://dx.doi.org/10.1002/(SICI)1521-3773(20000502)39:9
Abstract
The by no means trivial, solid-state reaction for the condensation of {(Mo)Mo5}12Fe30giant spheres commences through the water ligands and leads to oxo (or hydroxo) bridging. As the discrete icosahedral units approach each other, their oxygen atom bridges ultimately form covalent bonds (Fe-Fe 3.79 Å , see picture) to result in a symmetric layered structure.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Cluster Compounds; Magnetic Properties; Molybdenum; Polyoxometalates; Solid-state Chemistry |
| ID Code: | 59287 |
| Deposited On: | 07 Sep 2011 06:25 |
| Last Modified: | 16 Jul 2012 12:39 |
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