Müller, Achim ; Sarkar, Sabyasachi ; Shah, Syed Qaiser Nazir ; Bögge, Hartmut ; Schmidtmann, Marc ; Sarkar, Shatarupa ; Kögerler, Paul ; Hauptfleisch, Björn ; Trautwein, Alfred X. ; Schünemann, Volker (1999) Archimedean synthesis and magic numbers: "Sizing" giant molybdenum-oxide-based molecular spheres of the Keplerate type Angewandte Chemie International Edition, 38 (21). pp. 3238-3241. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/(SICI)1...
Related URL: http://dx.doi.org/10.1002/(SICI)1521-3773(19991102)38:21<3238::AID-ANIE3238>3.0.CO;2-6
Abstract
Pythagorean harmony can be found in the spherical polyoxometalate clusters described here (see illustration for an example of a structure), since there are interesting relationships between the so-called magic numbers (12, 32, 42, 72, 132) relevant for spherical viruses and the number of the building blocks in the cluster. The size of these Keplerate clusters can be tailored by varying the type of connections between the pentagons by means of different spacers.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Cage Compounds; Cluster Compounds; Polyoxometalates; Supramolecular Chemistry; Topology |
| ID Code: | 59286 |
| Deposited On: | 07 Sep 2011 06:25 |
| Last Modified: | 07 Sep 2011 06:25 |
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