Photochemical transformations-IV: Oxyfunctionalization of some saturated hydrocarbons with hydroxyl radicals

Sharma, S. N. ; Sonawane, H. R. ; Sukh Dev, (1985) Photochemical transformations-IV: Oxyfunctionalization of some saturated hydrocarbons with hydroxyl radicals Tetrahedron, 41 (12). pp. 2483-2491. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4020(01)96644-X

Abstract

It is shown that hydroxylation of saturated hydrocarbons by hydrogen peroxide occurs under the influence of light. This reaction has been investigated on acyclic, monocyclic and bicyclic hydrocarbons. These reactions were also studied using performic acid as the source of hydroxyl radicals and results compared with those obtained with peracetic acid. As expected, the preferred attack was on tertiary centres, followed by secondary and then primary.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:59202
Deposited On:03 Sep 2011 11:49
Last Modified:03 Sep 2011 11:49

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