Nayak, U. Ramdas. ; Santhanakrishnan, T. S. ; Sukh Dev, (1963) Studies in sesquiterpenes-XX: Acetoxymethylation of longifolene Tetrahedron, 19 (12). pp. 2281-2292. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0040-4020(63)85044-9
Abstract
Longifolene in Prins reaction with formaldehyde yielded the expected ω-acetoxymethyl longifolene, which was transformed into a number of interesting derivatives. Configuration of the Prins product has been arrived at by NMR measurements. The UV absorption of these derivatives show a considerable bathochromic shift with respect to those in the camphene series and this could be attributed to the slight twisting of the ethylenic linkage in longifolene and its derivatives.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 59190 |
| Deposited On: | 03 Sep 2011 11:39 |
| Last Modified: | 03 Sep 2011 11:39 |
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