Yadav, J. S. ; Subba Reddy, B. V. ; Subba Reddy, U. V. ; Krishna, A. D. (2007) Iodine/MeOH as a novel and versatile reagent system for the synthesis of α-ketothiocyanates Tetrahedron Letters, 48 (30). pp. 5243-5246. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2007.05.143
Abstract
Ketones possessing α-hydrogens undergo smooth thiocyanation with ammonium thiocyanate in the presence of molecular iodine in refluxing methanol to produce the corresponding α-ketothiocyanates in excellent yields with high selectivity. The use of iodine makes this procedure simple, convenient and cost effective.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Thiocyanation; Ketones; Iodine Catalysis; α-ketothiocyanates |
| ID Code: | 58919 |
| Deposited On: | 02 Sep 2011 03:27 |
| Last Modified: | 02 Sep 2011 03:27 |
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