Allylation and cyanation of aza-aromatics activated by chloroformate and a catalytic amount of iodine

Yadav, J. S. ; Reddy, B. V. S. ; Srinivas, M. ; Sathaiah, K. (2005) Allylation and cyanation of aza-aromatics activated by chloroformate and a catalytic amount of iodine Tetrahedron Letters, 46 (20). pp. 3489-3492. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2005.03.127

Abstract

Allyltrimethylsilane and trimethylsilyl cyanide undergo smooth addition to N-acylated quinolines in the presence of a catalytic amount of iodine to afford 2-allyl- and 2-cyano-1,2-dihydroquinoline derivatives, respectively in good yields with high chemo- and regioselectivity. A variety of functional groups such as alkyl, alkoxy, halo, and nitro functionalities are tolerated under the reaction conditions.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Aza-aromatics; Iodine Catalysis; Allylation; Cyanation
ID Code:58916
Deposited On:02 Sep 2011 03:21
Last Modified:02 Sep 2011 03:21

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