First example of molecular iodine-catalyzed allylation and alkynylation of cyclic allylic acetates

Yadav, J. S. ; Reddy, B. V. S. ; Vishweshwar Rao, K. ; Sarita Raj, K. ; Purushothama Rao, P. ; Prasad, A. R. ; Gunasekar, D. (2004) First example of molecular iodine-catalyzed allylation and alkynylation of cyclic allylic acetates Tetrahedron Letters, 45 (34). pp. 6505-6507. ISSN 0040-4039

Full text not available from this repository.

Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2004.06.116

Abstract

Cyclic allylic acetates undergo smooth allylation and alkynylation with allyltrimethylsilane and alkynyl silanes in the presence of molecular iodine under mild conditions to afford the corresponding allylated and alkynylated cyclohexene derivatives in good yields with high selectivity.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Allyl/Alkynyl Silanes; Molecular Iodine; Cyclic Allylic Acetates
ID Code:58909
Deposited On:02 Sep 2011 03:19
Last Modified:02 Sep 2011 03:19

Repository Staff Only: item control page