A formal total synthesis of crocacin C

Yadav, J. S. ; Venkatram Reddy, P. ; Chandraiah, L. (2007) A formal total synthesis of crocacin C Tetrahedron Letters, 48 (1). pp. 145-148. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2006.10.141

Abstract

An efficient total synthesis of a potent antifungal and moderate cytotoxic agent crocacin C is described. The synthesis involves the generation of four contiguous stereogenic centres via desymmetrization of a meso bicyclic dihydrofuran using asymmetric hydroboration.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Crocacin; Desymmetrization; Cross-metathesis; Modified Julia Olefination
ID Code:58906
Deposited On:02 Sep 2011 03:24
Last Modified:02 Sep 2011 03:24

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