Sabitha, Gowravaram ; Rama Subba Rao, V. ; Sudhakar, K. ; Raj Kumar, M. ; Venkata Reddy, E. ; Yadav, J. S. (2008) Study of conventional versus microwave-assisted reactions of 3,4-epoxyalcohols by CeCl3·7H2O: synthesis of tetrahydrofurans and 1-chloro-3-substituted-2-propanols Journal of Molecular Catalysis A: Chemical, 280 (1-2). pp. 16-19. ISSN 1381-1169
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.molcata.2007.09.004
Abstract
3,4-Epoxyalcohols undergo regioselective cyclization in the presence of CeCl3·7H2O in ref1uxing acetonitrile to afford tetrahydrofuran derivatives in good yields. On the other hand epoxyalcohols afforded 1-chloro-3-substituted-2-propanols under microwave irradiation using CeCl3·7H2O supported on SiO2 under solvent-free conditions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Epoxyalcohols; Conventional; Microwave; Tetrahydrofurans; Chloro Substituted Propanols |
| ID Code: | 58904 |
| Deposited On: | 02 Sep 2011 03:29 |
| Last Modified: | 02 Sep 2011 03:29 |
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