Yadav, J. S. ; Thirupathi Reddy, P. ; Nanda, S. ; Bhaskar Rao, A. (2002) Stereoselective synthesis of (R)-(−)-denopamine, (R)-(−)-tembamide and (R)-(−)-aegeline via asymmetric reduction of azidoketones by Daucus carota in aqueous medium Tetrahedron: Asymmetry, 12 (24). pp. 3381-3385. ISSN 0957-4166
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0957-4166(02)00024-1
Abstract
A simple and efficient stereoselective synthesis of (R)-denopamine and other naturally occurring hydroxy amides from optically active (R)-2-azido-1-arylethanols, is described for the first time via reduction of the corresponding α-azidoarylketones with enzymes from Daucus Carota root, under mild and environmentally friendly conditions. The products are formed with high degrees of enantioselectivity.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 58888 |
| Deposited On: | 02 Sep 2011 03:11 |
| Last Modified: | 02 Sep 2011 03:11 |
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