Mild and efficient method for the cleavage of cyclic and acyclic ethers by iodine under solvent-free conditions

Yadav, J. S. ; Reddy, B. V. S. ; Murali Krishna Reddy, P. ; Gupta, Manoj K. (2005) Mild and efficient method for the cleavage of cyclic and acyclic ethers by iodine under solvent-free conditions Tetrahedron Letters, 46 (49). pp. 8493-8495. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2005.10.017

Abstract

Ethers undergo smooth cleavage with acyl chlorides in the presence of a catalytic amount of elemental iodine under extremely mild conditions to give the corresponding halo esters. This new procedure offers significant advantages such as high conversions, short reaction times and enhanced selectivity together with mild reaction conditions, which makes it an attractive strategy.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Ethers; Acyl Chloride; Iodine
ID Code:58850
Deposited On:02 Sep 2011 03:22
Last Modified:02 Sep 2011 03:22

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