Yadav, J. S. ; Premalatha, K. ; Harshavardhan, S. J. ; Subba Reddy, B. V. (2008) The first stereoselective and the total synthesis of Leiocarpin C and total synthesis of (+)-Goniodiol Tetrahedron Letters, 49 (48). pp. 6765-6767. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2008.08.078
Abstract
The synthesis of the styryl lactone Leiocarpin C has been achieved in a highly stereoselective manner using Jacobsen's kinetic resolution, Sharpless asymmetric epoxidation and Sharpless asymmetric dihydroxylation as key steps. This is the first total synthesis of Leiocarpin C, and thus establishes for the first time the absolute stereochemistry of this natural product.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Styryl Lactones; Jacobsen's Kinetic Resolution; Sharpless Asymmetric Epoxidation; Sharpless Asymmetric Dihydroxylation |
| ID Code: | 58847 |
| Deposited On: | 02 Sep 2011 03:33 |
| Last Modified: | 02 Sep 2011 03:33 |
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