Eco-friendly heterogeneous solid acids as novel and recyclable catalysts in ionic medium for tetrahydropyranols

Yadav, J. S. ; Reddy, B. V. S. ; Sridhar Reddy, M. ; Niranjan, N. (2004) Eco-friendly heterogeneous solid acids as novel and recyclable catalysts in ionic medium for tetrahydropyranols Journal of Molecular Catalysis A: Chemical, 210 (1-2). pp. 99-103. ISSN 1381-1169

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.molcata.2003.08.024

Abstract

A variety of aldehydes and homoallylic alcohols undergo smoothly Prins-cyclization on the surface of solid acids such as H-ZSM-5 zeolite or Amberlyst-15® ion-exchange resin in 1-butyl-3-methylimidazolium hexafluorophosphate ionic liquid to afford the corresponding tetrahydropyranols in high yields with cis-diastereoselectivity. The recovered ionic liquid containing solid acid was recycled in subsequent runs without loss of activity.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Solid Acids; Homoallyl Alcohols; Tetrahydropyranols
ID Code:58844
Deposited On:02 Sep 2011 03:19
Last Modified:02 Sep 2011 03:19

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