Sabitha, Gowravaram ; Kiran Kumar Reddy, G. S. ; Bhaskar Reddy, K. ; Mallikarjuna Reddy, N. ; Yadav, J. S. (2005) Vanadium(III) chloride: a mild and efficient catalyst for the chemoselective deprotection of acetonides Journal of Molecular Catalysis A: Chemical, 238 (1-2). pp. 229-232. ISSN 1381-1169
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.molcata.2005.05.028
Abstract
Acetonides are selectively cleaved at room temperature by a catalytic amount of VCl3 in methanol to furnish the corresponding diols under mild conditions. Other hydroxyl protecting groups such as TBDMS, TBDPS, Ac, THP, Bn, prenyl, allyl present in the substrate were intact under the reaction conditions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Acetonides; Vanadium Chloride; Chemoselective; Diols |
| ID Code: | 58840 |
| Deposited On: | 02 Sep 2011 03:21 |
| Last Modified: | 02 Sep 2011 03:21 |
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