Yadav, J. S. ; Subba Reddy, B. V. ; Premalatha, K. ; Swamy, T. (2005) First example of the activation of polymethylhydrosiloxane with molecular iodine: a facile synthesis of 3,6-dihydropyran derivatives Tetrahedron Letters, 46 (15). pp. 2687-2690. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2005.02.068
Abstract
Glycals react rapidly with polymethylhydrosiloxane (PMHS) in the presence of a catalytic amount of molecular iodine under mild conditions to afford the corresponding 3,6-dihydropyran derivatives in excellent yields. Et3SiH/I2 was also found to be effective for this conversion.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Glycals; Molecular Iodine; PMHS; Dihydropyrans |
| ID Code: | 58836 |
| Deposited On: | 02 Sep 2011 03:21 |
| Last Modified: | 02 Sep 2011 03:21 |
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