Yadav, J. S. ; Rami Reddy, N. (2010) Stereoselective synthesis of C1-C9 and C9-C17 fragments of (+)-13-deoxytedanolide Tetrahedron, 66 (17). pp. 3265-3274. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tet.2010.01.023
Abstract
An efficient and highly stereoselective asymmetric synthesis of C1-C9 and C9-C17 fragments of (+)-13-deoxytedanolide have been achieved. Utilization of desymmetrization technique to prepare the triol with five stereogenic centers, regioselective Sharpless asymmetric dihydroxylation, Evans' aldol reaction, chiral methylation, and Wittig olefination are highlights of the synthesis.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | (+)-13-deoxytedanolide; Cytotoxicity; Evans' Aldol; Chiral Auxiliary; Cross-metathesis; Yamaguchi Macrolactonization; Regioselective Sharpless Asymmetric Dihydroxylation |
| ID Code: | 58833 |
| Deposited On: | 02 Sep 2011 03:39 |
| Last Modified: | 02 Sep 2011 03:39 |
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