Stereoselective total synthesis of (+)-sapinofuranone B

Yadav, J. S. ; Mandal, S. S. ; Reddy, J. S. S. ; Srihari, P. (2011) Stereoselective total synthesis of (+)-sapinofuranone B Tetrahedron, 67 (25). pp. 4620-4627. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tet.2011.04.072

Abstract

Two approaches for the total synthesis of (+)-sapinofuranone B have been described. The first strategy utilizes the methodology developed earlier in our group to get the chiral propargyl alcohol and the second strategy involves generation of threo-1,2-diol derivative by diastereoselective and enantioselective addition of [(Z)-γ-methoxymethoxyallyl]diisopinocampheylborane onto aldehyde and cross metathesis as the key steps.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:58816
Deposited On:02 Sep 2011 03:42
Last Modified:02 Sep 2011 03:42

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