Srihari, P. ; Kumaraswamy, B. ; Shankar, P. ; Ravishashidhar, V. ; Yadav, J. S. (2010) Stereoselective total synthesis of achaetolide and reconfirmation of its absolute configuration Tetrahedron Letters, 51 (47). pp. 6174-6176. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2010.09.070
Abstract
The stereoselective total synthesis of achaetolide 1 has been achieved and its absolute stereochemistry has been reconfirmed to be 3S,6R,7S,9R configuration. Keck allylation, Sharpless asymmetric dihydroxylation, and ring closing metathesis are the key steps involved in the target synthesis.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 58806 |
| Deposited On: | 02 Sep 2011 03:42 |
| Last Modified: | 02 Sep 2011 03:42 |
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